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Charged defects-controlled conductivity in Ge-ln-Se glasses

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Charged defects-controlled conductivity in Ge-ln-Se glasses

Auteurs : RBID : ISTEX:10853_1994_Article_BF00357356.pdf

Abstract

The variation of the d.c. electrical conductivity, σ, with composition and temperature was investigated for glasses of the Ge-In-Se system. The results indicate a decrease in the activation energy for electrical conductivity, ΔE, and an increase in σ on introduction of indium into Ge-Se glasses. The changes in ΔE and σ with composition (selenium content in the glasses) are identical for the Gex In5 Se95−x and Gex In8Se92−x families. The results have been traced to the conduction controlled by charged defects in these chalcogenide glasses. The changes in ΔE and σ have been explained by a shift in the Fermi level, being brought by the introduction of indium.

DOI: 10.1007/BF00357356

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<div type="abstract" xml:lang="eng">The variation of the d.c. electrical conductivity, σ, with composition and temperature was investigated for glasses of the Ge-In-Se system. The results indicate a decrease in the activation energy for electrical conductivity, ΔE, and an increase in σ on introduction of indium into Ge-Se glasses. The changes in ΔE and σ with composition (selenium content in the glasses) are identical for the Gex In5 Se95−x and Gex In8Se92−x families. The results have been traced to the conduction controlled by charged defects in these chalcogenide glasses. The changes in ΔE and σ have been explained by a shift in the Fermi level, being brought by the introduction of indium.</div>
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<abstract lang="eng">The variation of the d.c. electrical conductivity, σ, with composition and temperature was investigated for glasses of the Ge-In-Se system. The results indicate a decrease in the activation energy for electrical conductivity, ΔE, and an increase in σ on introduction of indium into Ge-Se glasses. The changes in ΔE and σ with composition (selenium content in the glasses) are identical for the Gex In5 Se95−x and Gex In8Se92−x families. The results have been traced to the conduction controlled by charged defects in these chalcogenide glasses. The changes in ΔE and σ have been explained by a shift in the Fermi level, being brought by the introduction of indium.</abstract>
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